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Highly soluble perylene tetracarboxylic diimides (PDI)‐tetrathiafulvalene (TTF) dyad and TTF‐PDI‐TTF triad
Author(s) -
Wang Chengyun,
Tang Wei,
Zhong Hanbin,
Zhang Xuechao,
Shen Yongjia
Publication year - 2009
Publication title -
journal of heterocyclic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.321
H-Index - 59
eISSN - 1943-5193
pISSN - 0022-152X
DOI - 10.1002/jhet.160
Subject(s) - tetrathiafulvalene , perylene , chemistry , triad (sociology) , fluorescence , acceptor , photochemistry , proton nmr , diimide , molecule , crystallography , stereochemistry , organic chemistry , psychology , physics , quantum mechanics , psychoanalysis , condensed matter physics
Two highly soluble donor‐σ‐acceptor and donor‐σ‐accepter‐σ‐donor type fluorescence switches consisting tetrathiafulvalene (TTF) and 3,4,9,10‐perylene tetracarboxylic diimides (PDI) were synthesized. The structure of the dyad and triad as well as their intermediates was characterized by 1 H NMR, 13 C NMR MS, elemental analysis. Their fluorescence behavior could be modulated by oxidization and reduction of the TTF unit using either chemical or electrochemical method. J. Heterocyclic Chem., (2009).