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Ozone distribution in the lower troposphere over complex terrain in Central Chile
Author(s) -
Seguel Rodrigo J.,
Mancilla Carlos A.,
Rondanelli Roberto,
Leiva Manuel A.,
Morales Raúl G. E.
Publication year - 2013
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
eISSN - 2169-8996
pISSN - 2169-897X
DOI - 10.1002/jgrd.50293
Subject(s) - structural basin , troposphere , subsidence , ozone , atmospheric sciences , environmental science , inversion (geology) , tropospheric ozone , terrain , pollution , climatology , geology , geography , geomorphology , meteorology , ecology , cartography , biology
Observations were performed in 12 communities of Central Chile in order to determine the horizontal gradients of ozone in the Santiago Basin and surrounding valleys. Higher ozone mixing ratios were found northeast of the Santiago Basin and included east of the Aconcagua Valley (~70 km from Santiago) suggesting that photochemical pollution produced in Santiago is capable of passing through the Chacabuco mountain chain (~1.3 km) and have impact downwind from the regions with the largest NO x and VOC emissions. To complement existing surface observations, ozonesonde and tethersonde campaigns were performed in the Santiago Basin and the Aconcagua Valley. The results suggest ozone can accumulate in layers aloft (e.g., >102 ppb at 2 km) similarly to layers observed in complex topography coastal regions like Southern California. Layers of significant ozone concentrations having a near surface origin were observed above the mixed layer and below the subsidence inversion base. We propose that the ozone in this residual layer can be transported large distances (at least to 70 km) to further penetrate into the local environment under conditions of a well‐mixed boundary layer.