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Decadal time series of tropospheric abundance of N 2 O isotopomers and isotopologues in the Northern Hemisphere obtained by the long‐term observation at Hateruma Island, Japan
Author(s) -
Toyoda Sake,
Kuroki Natsuko,
Yoshida Naohiro,
Ishijima Kentaro,
Tohjima Yasunori,
Machida Toshinobu
Publication year - 2013
Publication title -
journal of geophysical research: atmospheres
Language(s) - English
Resource type - Journals
eISSN - 2169-8996
pISSN - 2169-897X
DOI - 10.1002/jgrd.50221
Subject(s) - isotopologue , northern hemisphere , southern hemisphere , isotope , isotopomers , troposphere , atmospheric sciences , mixing ratio , isotopes of nitrogen , stable isotope ratio , nitrous oxide , chemistry , nitrogen , geology , climatology , physics , organic chemistry , quantum mechanics , molecule
Decadal time series and short‐term temporal variations in mixing ratio of atmospheric nitrous oxide (N 2 O) and abundance of its isotopomers ( 14 N 15 N 16 O and 15 N 14 N 16 O) and isotopologue ( 14 N 14 N 18 O) relative to 14 N 14 N 16 O have been observed for the first time in the Northern Hemisphere at Hateruma Island (HAT), Japan during 1999–2010 by monthly air sampling. Results show that the bulk nitrogen isotope ratio δ 15 N bulk decreased at the rate of −0.023 ± 0.006‰ yr −1 , although the N 2 O mixing ratio increased at the rate of about 0.7 nmol mol −1 yr −1 (ppb yr −1 ) during the period. Isotope budget calculation with the δ 15 N bulk trend supports the earlier estimates showing that the isotopically light sources such as agriculture and industry contribute to the increase of atmospheric N 2 O. However, the rate of decrease of δ 15 N bulk is slightly smaller in magnitude than the rates obtained virtually for the 20th century from firn air in polar regions and surface air in the Southern Hemisphere (Tasmania and Antarctica), which suggests greater contribution of 15 N‐enriched N 2 O sources in recent years or in the extra‐polar Northern Hemisphere. In contrast, the oxygen isotope ratio ( δ 18 O) and intramolecular 15 N site preference ( SP , difference between isotope ratios at central and terminal nitrogen atoms) of N 2 O showed no significant trends, contrary to previous reports. Results show that no significant seasonal variation exists in δ 15 N bulk , δ 18 O, and SP of N 2 O at HAT in the past decade within the limits of our sampling frequency and analytical precision.