Kinetics of aqueous phase hydrogenation of maleic acid to succinic acid over an Ru/Al 2 O 3  catalyst | Zendy

Vaidya Prakash D | Zendy; Mahajani Vijaykumar V | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Kinetics of aqueous phase hydrogenation of maleic acid to succinic acid over an Ru/Al 2 O 3 catalyst

Author(s) -

Vaidya Prakash D,

Mahajani Vijaykumar V

Publication year - 2003

Publication title -

journal of chemical technology and biotechnology

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.64

H-Index - 117

eISSN - 1097-4660

pISSN - 0268-2575

DOI - 10.1002/jctb.816

Subject(s) - maleic acid , catalysis , partial pressure , hydrogen , succinic acid , aqueous solution , chemistry , kinetics , inorganic chemistry , reaction rate , slurry , chemical kinetics , langmuir , rate equation , organic chemistry , materials science , polymer , oxygen , physics , copolymer , composite material , quantum mechanics

The kinetics of aqueous phase catalytic hydrogenation of maleic acid to succinic acid were studied in a slurry reactor between 323 and 353 K using a hydrogen partial pressure range of 1.03–2.06 MPa, with a 5% Ru/Al 2 O 3 catalyst. The initial rate data were analyzed using a power law model. Above 1.72 MPa hydrogen partial pressure, the reaction was zero order with respect to hydrogen. Based on this hydrogen pressure effect, a Langmuir–Hinshelwood rate model was proposed to which the rate data could be fitted well. Copyright © 2003 Society of Chemical Industry

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research