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Facile preparation of hierarchical heterostructured TiO 2 /Bi/Bi 2 MoO 6 photocatalyst for phocatalytic degradation of toluene gas
Author(s) -
Sun Zhiguo,
Fan Jiaming,
Feng Run,
Wang Menglu,
Zhou Yue,
Zhang Li
Publication year - 2021
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.6698
Subject(s) - photocatalysis , materials science , toluene , catalysis , degradation (telecommunications) , specific surface area , adsorption , chemical engineering , nanotechnology , band gap , nanoparticle , optoelectronics , chemistry , organic chemistry , computer science , telecommunications , engineering
BACKGROUND In recent years, the emission of volatile organic compounds (VOCs) from different sources has caused huge environmental problems. As a ‘green’ terminal treatment technology, photocatalytic technology is a competitive technology that has practical application prospects for the emission reduction of VOCs. The core problem of photocatalysis technology is constructing a photocatalyst with higher activity. RESULTS In this work, a new hierarchical heterostructured photocatalyst of TiO 2 /Bi/Bi 2 MoO 6 was facilely fabricated by solvothermal method with the TiO 2 nanoparticles uniformly distributed on the surface of flower‐like Bi 2 MoO 6 nanospheres. Compared with the bare flower‐like Bi 2 MoO 6 nanospheres, the band gap width of TiO 2 /Bi/Bi 2 MoO 6 is wider, which helps to improve the Fermi level‐derived oxidation–reduction capacity of the catalyst. N 2 adsorption–desorption experiments show that the composite material has a larger specific surface area, which is beneficial to improve the mass transfer efficiency in the gas–solid heterogeneous reaction. Photocatalytic data display that, under irradiation by Xenon lamp for 2 h, the degradation rate of toluene gas over TiO 2 /Bi/Bi 2 MoO 6 reached 26.08%, which is 17.92% higher than that of the bare Bi 2 MoO 6 nanospheres. CONCLUSION These results indicate that coupling TiO 2 could significantly enhance the photocatalytic degradation effect of toluene over the hierarchical heterostructured TiO 2 /Bi/Bi 2 MoO 6 , and this has practical application prospects for the use of photocatalytic technology to treat VOCs pollution. © 2021 Society of Chemical Industry