Premium
Deactivation and regeneration of Pt‐modified zeolite Beta–Bindzil extrudates in n ‐hexane hydroisomerization
Author(s) -
Vajglová Zuzana,
Kumar Narendra,
Peurla Markus,
Hupa Leena,
Semikin Kirill,
Sladkovskiy Dmitry A,
Murzin Dmitry Yu
Publication year - 2021
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.6685
Subject(s) - bifunctional , catalysis , selectivity , hexane , zeolite , chemistry , metal , bifunctional catalyst , acid strength , chemical engineering , inorganic chemistry , nuclear chemistry , organic chemistry , engineering
BACKGROUND The metal–acid bifunctional catalysts are widely used in many industrially significant chemical processes, including hydroisomerization of n ‐hexane. Deactivation and regeneration of metal–acid bifunctional extrudates was investigated in continuous n ‐hexane hydroisomerization in a fixed‐bed reactor. Four Pt/H‐Beta‐25 catalysts containing 30% Bindzil binder were prepared with the same composition and controlled metal deposition. RESULTS Different preparation steps led to differences in the mechanical strength, Pt particle size, acidity and strength, metal‐to‐acid site ( c Pt / c AS ) ratio and proximity between two types of active sites. A very slow deactivation and high selectivity to C 6 isomers was obtained when Pt was deposited on H‐Beta‐25 zeolite. CONCLUSION Initial selectivity to the desired products was correlated with the physicochemical properties of the catalysts. Location of the metal has a larger influence on catalyst deactivation of the bifunctional catalysts rather than the metal‐to‐acid site ratio or site proximity. Decline of n ‐hexane conversion and selectivity to C 6 isomers were correlated with changes in the textural properties and acidity of the deactivated catalyst, respectively. © 2021 The Authors. Journal of Chemical Technology & Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.