Premium
Metal–organic frameworks derived magnetic Fe 3 O 4 /C for catalytic transfer hydrogenation of furfural to furfuryl alcohol
Author(s) -
Jiang Shanshan,
Huang Jin,
Wang Yue,
Lu Shiyu,
Li Pei,
Li Cuiqin,
Li Feng
Publication year - 2021
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.6577
Subject(s) - furfural , furfuryl alcohol , catalysis , calcination , metal organic framework , carbothermic reaction , carbonization , transfer hydrogenation , materials science , metal , hydrogen storage , hydrogen , borane , furan , chemical engineering , inorganic chemistry , chemistry , carbide , organic chemistry , metallurgy , ruthenium , adsorption , engineering
Abstact BACKGROUND Fe based metal organic frameworks (Fe‐MOFs) were prepared by solvothermal method, and carbon loaded Fe 3 O 4 (Fe 3 O 4 /C) was prepared by pyrolytic carbonization and carbothermal reduction. RESULTS Various analytical techniques were used to characterize the physicochemical structure of Fe‐MOFs and Fe 3 O 4 /C under different solvothermal and calcination conditions. Fe 3 O 4 /C was then employed as a catalyst for the catalytic transfer hydrogenation of furfural with alcohol as a hydrogen donor, and the effect of hydrogen donor species, reaction temperature, and reaction time were investigated. CONCLUSION The Fe 3 O 4 /C catalyst could be easily collected with a magnet and reused for four runs without significant loss of its catalytic. A possible mechanism for the catalytic transfer hydrogenation of furfural over Fe 3 O 4 /C was proposed. © 2020 Society of Chemical Industry (SCI)
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom