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Metal–organic frameworks derived magnetic Fe 3 O 4 /C for catalytic transfer hydrogenation of furfural to furfuryl alcohol
Author(s) -
Jiang Shanshan,
Huang Jin,
Wang Yue,
Lu Shiyu,
Li Pei,
Li Cuiqin,
Li Feng
Publication year - 2021
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.6577
Subject(s) - furfural , furfuryl alcohol , catalysis , calcination , metal organic framework , carbothermic reaction , carbonization , transfer hydrogenation , materials science , metal , hydrogen storage , hydrogen , borane , furan , chemical engineering , inorganic chemistry , chemistry , carbide , organic chemistry , metallurgy , ruthenium , adsorption , engineering
Abstact BACKGROUND Fe based metal organic frameworks (Fe‐MOFs) were prepared by solvothermal method, and carbon loaded Fe 3 O 4 (Fe 3 O 4 /C) was prepared by pyrolytic carbonization and carbothermal reduction. RESULTS Various analytical techniques were used to characterize the physicochemical structure of Fe‐MOFs and Fe 3 O 4 /C under different solvothermal and calcination conditions. Fe 3 O 4 /C was then employed as a catalyst for the catalytic transfer hydrogenation of furfural with alcohol as a hydrogen donor, and the effect of hydrogen donor species, reaction temperature, and reaction time were investigated. CONCLUSION The Fe 3 O 4 /C catalyst could be easily collected with a magnet and reused for four runs without significant loss of its catalytic. A possible mechanism for the catalytic transfer hydrogenation of furfural over Fe 3 O 4 /C was proposed. © 2020 Society of Chemical Industry (SCI)

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