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Hydrothermal synthesis of a two‐dimensional g‐C 3 N 4 /MoS 2 /MnOOH composite material and its potential application as photocatalyst
Author(s) -
JiménezRangel Kristel Yurien,
LartundoRojas Luis,
GarcíaGarcía Alejandra,
CipagautaDíaz Sandra,
Mantilla Angeles,
SamaniegoBenítez José Enrique
Publication year - 2019
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.6088
Subject(s) - photocatalysis , x ray photoelectron spectroscopy , materials science , band gap , scanning electron microscope , diffuse reflectance infrared fourier transform , composite number , hydrothermal circulation , water splitting , analytical chemistry (journal) , chemical engineering , nuclear chemistry , composite material , chemistry , catalysis , optoelectronics , organic chemistry , engineering
BACKGROUND Environmental pollution and energy crisis are nowadays considered among the most important problems facing humanity. Several strategies have been proposed to solve them, being photocatalysis a very promising one because of its ease of application and low cost. In the search for active photocatalysts, those based on graphite‐like carbon nitride (g‐C 3 N 4 ) are becoming good alternatives for various reactions. In this work, the properties of g‐C 3 N 4 /MoS 2 /MnOOH composite material and its photocatalytic behavior for the production of hydrogen (H 2 ) under UV radiation were investigated. RESULTS The composite material was synthesized by applying a combination of thermal condensation and hydrothermal methods. According to the results of X‐ray diffraction (XRD), ultraviolet diffuse reflectance spectroscopy (UV‐DRS), scanning electron microscopy (SEM), X‐ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM), good dispersion of the phases and the formation of a heterojunction were observed. The band gap value of the composite material, calculated by the Kubelka–Munk equation using the values obtained from UV‐DRS analysis, was lower than those of the individual components, while it also had a much longer electron–hole recombination time, according to photoluminescence analysis. As a consequence of a synergistic effect, the activity of the proposed composite photocatalyst was superior in the reaction of water splitting, with a kinetic constant of 466 μmol h −1 and a production rate of 1750 μmol H 2g cat − 1h −1 (50 and 21% higher than those obtained with MoS 2 and g‐C 3 N 4 , respectively). CONCLUSION Because of its high activity and stability, g‐C 3 N 4 /MoS 2 /MnOOH composite photocatalyst is an excellent alternative for H 2 production by the water splitting reaction. © 2019 Society of Chemical Industry