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Reject water characterization and treatment through short‐cut nitrification/denitrification: assessing the effect of temperature and type of substrate
Author(s) -
Noutsopoulos Constantinos,
Mamais Daniel,
Statiris Evangelos,
Lerias Eleftherios,
Malamis Simos,
Andreadakis Andreas
Publication year - 2018
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.5745
Subject(s) - nitrification , denitrification , chemistry , nitrogen , wastewater , ammonium , sewage treatment , arrhenius equation , pulp and paper industry , ammonia , total organic carbon , biodegradation , carbon fibers , environmental chemistry , environmental engineering , environmental science , materials science , organic chemistry , activation energy , composite number , engineering , composite material
BACKGROUND The objectives of this study were to provide a detailed qualitative and quantitative characterization of different reject water types and to evaluate the effect of temperature and type of external organic carbon source on short‐cut nitrification/denitrification process performance for the treatment of reject water with a high ammonia content. RESULTS According to the results reject water originating from the sludge dewatering unit is characterized by a high ammonium‐nitrogen content which can be further increased upon pre‐treating the sludge in a thermal‐hydrolysis unit, a low carbon to nitrogen ratio, a low biodegradability and contributes approximately 75% of the total ammonium‐nitrogen load of the recycled flows. It is anticipated that the process can be sustained even at low temperatures (15°C). The temperature effect on both nitritation/denitritation rates is described by an Arrhenius equation with activation energies equal to 37.6 and 39.6 kJ mol −1 respectively. The addition of an organic carbon source rich in easily biodegradable compounds can provide for the achievement of high denitritation rates (in the order of 10 mgNO 2 ‐N gVSS‐1 h −1 ). CONCLUSION An interesting low cost option to reserve on‐site an easily biodegradable organic carbon source by integrating different processes in a wastewater treatment plant is primary sludge hydrolysis. © 2018 Society of Chemical Industry