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Efficient solvent extraction of phosphoric acid with dibutyl sulfoxide
Author(s) -
Chen Ming,
Li Jun,
Jin Yang,
Luo Jianhong,
Zhu Xinhua,
Yu Defang
Publication year - 2018
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.5377
Subject(s) - phosphoric acid , chemistry , extraction (chemistry) , dimethyl sulfoxide , solvent , sulfoxide , nuclear chemistry , inorganic chemistry , organic chemistry
BACKGROUND In china, the grade of phosphate ores has decreased sharply in recent years. Existing solvents are inefficient for the extraction of wet‐process phosphoric acid produced by low‐grade phosphate ores. Organic solvent dibutyl sulfoxide was developed to improve the extraction capacity of wet‐process phosphoric acid, especially at low‐acid concentration. RESULTS The effects of extraction time, temperature, phosphoric acid concentration and impurities concentration on the extraction were investigated. The extraction process is exothermic and the enthalpy change is –5.86 kJ mol ‐1 . Dibutyl sulfoxide is relatively selective for Mg 2+ and Al 3+ while the selectivities of Fe 3+ , F ‐ and SO 4 2‐ are moderate. The liquid–liquid equilibrium of water–dibutyl sulfoxide–phosphoric acid system was determined at 298.15 K. The stability of dibutyl sulfoxide and the process flows of extraction, scrubbing and stripping were investigated. The extraction mechanism of dibutyl sulfoxide for phosphoric acid was proposed and the extracted complex H 3 PO 4 ·0.3DBSO was obtained. CONCLUSION Dibutyl sulfoxide is demonstrated to be a powerful solvent for the extraction of wet‐process phosphoric acid even at low concentrations. Dibutyl sulfoxide can be a potential supplemental organic solvent for the extraction of wet‐process phosphoric acid produced by low‐grade phosphate ores. © 2017 Society of Chemical Industry