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Transition metal oxide catalysts as an alternative for the oxidation of nitrogen monoxide to nitrogen dioxide: kinetic modelling at high space velocity
Author(s) -
Tecchio Leonardo,
Marín Pablo,
Díez Fernando V,
Ordóñez Salvador
Publication year - 2016
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.4575
Subject(s) - catalysis , space velocity , oxide , monolith , transition metal , isothermal process , nitrogen , inorganic chemistry , materials science , carbon monoxide , metal , oxygen , chemistry , chemical engineering , metallurgy , thermodynamics , organic chemistry , physics , engineering , selectivity
BACKGROUND The oxidation of NO to NO 2 is a key step in environmental pollution abatement techniques, such as ‘fast‐ SCR ’ or diesel engine catalytic traps. In both cases, the conversion of an important fraction of NO into NO 2 is a key step. In this work, two commercially available transition metal oxide catalysts, CuMn and CuCr ‐based, are studied as an alternative to noble metal catalysts (a Pt/ Al 2 O 3 catalyst is used as reference catalyst). RESULTS Steady NO conversion is obtained after the first 1–2 h of operation. The experiments, carried out in an isothermal fixed‐bed reactor operating at high space velocities (5.60 g cat min mol ‐1 , GHSV monolith ‐eq. = 83 000 h ‐1 ) with 500 ppm NO and 20% oxygen, showed that the optimum operating temperature is 380 °C for the CuMn catalyst, 430 °C for the CuCr catalyst and 366 °C for a 0.5% Pt/ Al 2 O 3 catalyst. CONCLUSIONS The CuMn catalyst performed very similarly to the 0.5% Pt/ Al 2 O 3 catalyst in the vicinity of 380 °C, being a good and cheaper alternative to noble metal catalysts. Kinetic measurements obtained under different conditions, e.g. 3.73–5.60 g cat min mol ‐1 ( GHSV monolith ‐eq. = 83 000–125 000 h ‐1 ), 300–900 ppm NO , 1–20% oxygen concentration and 330–480 °C, have been found to fit a mechanistic kinetic model based on the reaction between gas nitrogen oxide and adsorbed oxygen. © 2014 Society of Chemical Industry