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Release of potentially fermentable sugars during dilute acid treatments of Bermuda grass NK37 ( Cynodon dactylon) for second‐generation ethanol production
Author(s) -
Canizo Jesica R.,
CortesCallejas María L.,
DavilaGomez Francisco J.,
HerediaOlea Erick,
PerezCarrillo Esther,
SernaSaldívar Sergio O.
Publication year - 2014
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.4280
Subject(s) - furfural , xylose , chemistry , acetic acid , hydrolysis , arabinose , cynodon dactylon , ethanol fuel , fermentation , ethanol , enzymatic hydrolysis , food science , forage , agronomy , biochemistry , biology , catalysis
BACKGROUND Bermuda grass is an irrigated forage crop adapted to arid and subtropical zones. This grass can be effectively bioconverted into second‐generation fuel ethanol. The aim was to optimize different acid hydrolyses conditions to maximize the release of C5 and C6 sugars from the forage with minimal production of microbial inhibitors. RESULTS The optimum conditions for H 2 SO 4 were 12.5% solid to liquid, an acid concentration of 1.25%, and 75 min hydrolysis. The efficiencies after dilute acid and enzymatic treatments were 92.5, 73.5 and 89.9% for glucose, xylose and arabinose, respectively and the amounts of inhibitors were 8.2 kg m ‐3 of acetic acid, 0.5 kg m ‐3 of HMF , and 1.7 kg m ‐3 furfural. For the HCl pretreatment, the optimum conditions were 12.5% solid to liquid fraction, 1.25% acid concentration and 37.5 min hydrolysis. These conditions released 56.2% glucose, 86.2% xylose and 48.3% of arabinose and generated 9 kg m ‐3 of acetic acid, 0.5 kg m ‐3 of HMF , and 2.6 kg m ‐3 of furfural. CONCLUSION Dual chemical and enzyme conversions are promising for production of second‐generation ethanol from Bermuda grass. © 2013 Society of Chemical Industry