Premium
Heterogeneous photo‐Fenton oxidation of Acid Orange II over iron–sewage sludge derived carbon under visible irradiation
Author(s) -
Tu Yuting,
Xiong Ya,
Descorme Claude,
Kong Lingjun,
Tian Shuanghong
Publication year - 2014
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.4151
Subject(s) - catalysis , chemistry , sewage sludge , nuclear chemistry , mineralization (soil science) , leaching (pedology) , adsorption , photocatalysis , orange (colour) , iron oxide , pyrolysis , fourier transform infrared spectroscopy , sewage , waste management , chemical engineering , organic chemistry , food science , environmental science , nitrogen , soil science , engineering , soil water
BACKGROUND The disposal of sewage sludge has become an issue of particular concern due to its continuously increasing quantity. In this study, sewage sludge derived carbon ( SC ) was employed as support for iron‐oxide‐containing catalyst ( FeSC ). The catalysts were characterized in terms of inorganic elemental composition, XRD , SEM and TGA‐FTIR . The catalytic activity of the catalyst was evaluated from the discoloration and mineralization of acid orange II ( AOII ) in the presence of H 2 O 2 and visible light.RESULTS The FeSC catalyst pyrolyzed at 800 o C for 2 h displayed the highest catalytic activity. Almost complete discoloration and 67% mineralization of 100 mg L –1 AOII were achieved after 30 min adsorption and 60 min oxidation under visible light irradiation, using 1.5 g L –1 catalyst, 15.0 mmol L –1 H 2 O 2 and initial pH 4.0. The prepared FeSC also exhibited very limited iron leaching (0.56 mg L –1 after 90 min reaction) and high stability since the activity remained constant over ten consecutive runs.CONCLUSIONS This study demonstrated the high activity and stability of the sewage sludge‐derived carbon‐supported iron oxide catalyst in photo‐Fenton‐like reaction. © 2013 Society of Chemical Industry