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Visible light photocatalytic activity of TiO 2 /heat‐treated PVC film
Author(s) -
Li Xueyan,
Shi Lei,
Wang Desong,
Luo Qingzhi,
An Jing
Publication year - 2012
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.3747
Subject(s) - photocatalysis , photodegradation , visible spectrum , materials science , anatase , rhodamine b , polymer , conjugated system , chemical engineering , photochemistry , composite material , organic chemistry , catalysis , chemistry , optoelectronics , engineering
BACKGROUND: Semiconductor TiO 2 has been investigated extensively due to its chemical stability, nontoxicity and inexpensiveness. However, the wide band gap of anatase TiO 2 (about 3.2 eV) only allows it to absorb UV light. TiO 2 nanoparticles modified by conditional conjugated polymers show excellent photocatalytic activity under visible light. However, these conjugated polymers are not only expensive, but also difficult to process. Polyvinyl chloride (PVC) was heat‐treated at high temperature to remove HCl and a CC conjugated chain structure was obtained. When TiO 2 nanoparticles were dispersed into the conjugated polymer film derived from PVC, this composites film exhibited high visible light photocatalytic activity. RESULTS: The photocatalytic activity of TiO 2 /heat‐treated PVC (HTPVC) film was investigated by degrading Rhodamine B (RhB) under visible light irradiation. The photodegradation of RhB follows apparent first‐order kinetics. The rate constants of RhB photodegradation in the presence of the TiO 2 /HTPVC films with different mass content of TiO 2 are 16–56 and 4–14 times that obtained in the presence of the pure HTPVC and TiO 2 /polymethyl methacrylate (PMMA) composite film, respectively. The TiO 2 /HTPVC film showed excellent photocatalytic activity and stability after 10 cycles under visible light irradiation. CONCLUSION: TiO 2 /HTPVC film exhibits high visible light photocatalytic activity and stability. Copyright © 2012 Society of Chemical Industry