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Activity of ruthenium hydrogenation catalysts in copper(II) formate decomposition
Author(s) -
Kluson Petr,
Cerveny Libor,
Krivska Marie,
Had Jiri,
Laurentova Simona
Publication year - 1994
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.280590415
Subject(s) - ruthenium , catalysis , ruthenium oxide , bimetallic strip , copper , formate , inorganic chemistry , incipient wetness impregnation , chemistry , decomposition , methyl formate , nuclear chemistry , materials science , organic chemistry , selectivity
Charcoal‐, silica‐, alumina‐ and titanium(IV) oxide‐supported ruthenium catalysts, prepared by conventional impregnation and incipient wetness methods from a ruthenium(III) oxide precursor were tested in copper(II) formate decomposition in aqueous solution. Such a reaction was found to be an efficient and simple activity test of charcoal‐supported catalysts. The application of this reaction for a bimetallic ruthenium–copper catalyst preparation was also suggested. Experimental results were compared with those obtained using commercial catalysts and ruthenium black.

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