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Photodegradation of four fluoroquinolone compounds by titanium dioxide under simulated solar light irradiation
Author(s) -
Li Weihong,
Guo Changsheng,
Su Bin,
Xu Jian
Publication year - 2012
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.2759
Subject(s) - ofloxacin , norfloxacin , photocatalysis , photodegradation , irradiation , enrofloxacin , titanium dioxide , hydrogen peroxide , nuclear chemistry , chemistry , ciprofloxacin , reaction rate constant , materials science , kinetics , organic chemistry , antibiotics , catalysis , biochemistry , quantum mechanics , nuclear physics , physics , metallurgy
BACKGROUND; In this study, simultaneous photocatalytic degradation of four fluoroquinolone (FQ) compounds (i.e. ofloxacin, norfloxacin, ciprofloxacin and enrofloxacin) was investigated in TiO 2 suspensions under simulated solar light irradiation. Effects of experimental variables including pH, TiO 2 dosage, initial substrate concentration and hydrogen peroxide (H 2 O 2 ) on the degradation processes were also investigated. RESULTS: The antibiotics degradation was pH‐influenced. The photocatalytic reaction followed the pseudo‐first‐order model, with reaction rate constants ( k ) 0.026, 0.027, 0.022 and 0.026 min −1 for ofloxacin, norfloxacin, ciprofloxacin and enrofloxacin, respectively. Complete elimination of four FQs was achieved in a reaction system composed of 0.5 g L −1 of TiO 2 and 82.5 mg L −1 of H 2 O 2 at pH 6 after 90 min irradiation. Mineralization of FQs during TiO 2 photocatalysis was slower than the FQs conversion, and the antibacterial activity of the four FQs was completely removed by TiO 2 under simulated solar light irradiation. CONCLUSION: The four FQs can be simultaneously degraded and mineralized with commercially available TiO 2 under simulated solar light irradiation. Microbiological analysis showed that the antibacterial activity of the four FQs was completely removed. These results are helpful for antibiotics removal in the environment, and for exploring new technology for wastewater treatment. Copyright © 2012 Society of Chemical Industry