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Equilibrium and kinetic studies on the extraction of gadolinium(III) from nitrate medium by di‐2‐ethylhexylphosphoric acid in kerosene using a single drop technique
Author(s) -
ElHefny Naglaa E,
ElDessouky Sahar I
Publication year - 2006
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.1408
Subject(s) - kerosene , equilibrium constant , extraction (chemistry) , chemistry , drop (telecommunication) , endothermic process , analytical chemistry (journal) , reaction rate constant , kinetic energy , liquid–liquid extraction , partition coefficient , chromatography , kinetics , inorganic chemistry , organic chemistry , telecommunications , physics , adsorption , quantum mechanics , computer science
The liquid–liquid extraction of Gd(III) from aqueous nitrate medium was studied using di‐2‐ethylhexylphosphoric acid (HDEHP) in kerosene. On the basis of the slope analysis data, the composition of the extracted species was found to be [Gd A 3 (HA)] with the extraction equilibrium constant ( K ex ) = (1.48 ± 0.042) × 10 −12 mol dm −3 . The results of the effect of temperature on the value of the equilibrium extraction constant indicated the endothermic character of the extraction system. The kinetics of the forward extraction of Gd 3+ from nitrate medium by HDEHP in kerosene was investigated using the single drop column technique. The rate of flux (mass transfer per unit area) was found to be proportional to [Gd(III)], [H 2 A 2 ] (o) , [NO 3 − ], and [H + ] −1 in the liquid drop organic phase. The forward extraction rate constant, k f , was 2.24 × 10 −3 m s −1 using the equation:$$R_{{{\rm{f}}}} = 2.24 \times 10^{-3}[\hbox{Gd}^{3+}] [\overline{\hbox{HDEHP}}] [{\hbox{NO}_{3}}^{-}] [\hbox{H}^{+}]^{-1} \hbox{kmol m}^{-2} \hbox{s}^{-1}$$Copyright © 2005 Society of Chemical Industry