Premium
Effects of anions on the photocatalytic and photoelectrocatalytic degradation of reactive dye in a packed‐bed reactor
Author(s) -
Zhang Wenbing,
An Taicheng,
Cui Mingchao,
Sheng Guoying,
Fu Jiamo
Publication year - 2005
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/jctb.1185
Subject(s) - photocatalysis , degradation (telecommunications) , reactive dye , chemistry , inorganic ions , methyl orange , catalysis , nuclear chemistry , ion , photochemistry , inorganic chemistry , organic chemistry , dyeing , telecommunications , computer science
The effects of various anions, Cl − , ClO 4 − , SO 4 2− , NO 3 − , HCO 3 − , H 2 PO 4 − and C 2 O 4 2− , on the photocatalytic and photoelectrocatalytic degradation of reactive Brilliant Orange K‐R have been investigated in a packed‐bed photoelectrocatalytic reactor. It was found that the nature and concentrations of these inorganic anions significantly affected the photocatalytic and photoelectrocatalytic degradation performance of the reactive dye. The results indicated that the external electric field was successfully applied to improve the photocatalytic efficiency of reactive Brilliant Orange K‐R in the presence of Cl − , especially at higher concentrations, while other inorganic anions displayed more or less negative effects on the degradation of the dye. The strongest inhibition effect on photocatalytic and photoelectrocatalytic degradation of the dye was observed in the presence of HCO 3 − ions. Copyright © 2004 Society of Chemical Industry