Premium
Cover: Journal of the Chinese Chemical Society 9/2020
Publication year - 2020
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.202080901
Subject(s) - denticity , chemistry , stereochemistry , crystallography , crystal structure
In this figure, the authors have scrutinized eight novel monodentate (1‐4) and bidentate (1 ’ ‐4 ’ ) derivatives of 2,5‐diX‐cyclopentasilylene‐2,4‐dienes (X = NH 2 , OH, PH 2 , and SH), and their corresponding complexes with Rh atom (1 Rh ‐4 Rh and 1 ’ Rh ‐4 ’ Rh , respectively), at M06/6‐311++G** level of theory. The overall orders of σ‐donation ability of monodentate and bidentate ligands are 1>2>3>4 and 1 ’ >2 ’ >3 ’ >4 ’ , respectively. More details about this figure will be discussed by Prof. Mohamad Z. Kassaee and his co‐worker on page 1544‐1551 in this issue.