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Silver catalyzed pyridine‐directed acceptorless dehydrogenation of secondary alcohols
Author(s) -
Zhuang Xin,
Tao Jing,
Luo Zhen,
Hong ChuanMing,
Liu ZhengQiang,
Li QingHua,
Ren LiQing,
Luo QunLi,
Liu TangLin
Publication year - 2021
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.202000517
Subject(s) - dehydrogenation , chemistry , catalysis , pyridine , yield (engineering) , atom economy , organic chemistry , functional group , hydrogen , combinatorial chemistry , metallurgy , materials science , polymer
A silver catalyzed pyridine‐directed acceptorless dehydrogenation of secondary benzyl alcohols was developed. This general procedure delivers ketones with high atom‐economy and hydrogen was the sole byproduct. This dehydrogenation reaction has a good functional group tolerance and high efficiency (up to 90% yield and 10,000/1 substrates‐to‐catalyst ratio).