Silver catalyzed pyridine‐directed acceptorless dehydrogenation of secondary alcohols | Zendy

Zhuang Xin | Zendy; Tao Jing | Zendy; Luo Zhen | Zendy; Hong ChuanMing | Zendy; Liu ZhengQiang | Zendy; Li QingHua | Zendy; Ren LiQing | Zendy; Luo QunLi | Zendy; Liu TangLin | Zendy

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Silver catalyzed pyridine‐directed acceptorless dehydrogenation of secondary alcohols

Author(s) -

Zhuang Xin,

Tao Jing,

Luo Zhen,

Hong ChuanMing,

Liu ZhengQiang,

Li QingHua,

Ren LiQing,

Luo QunLi,

Liu TangLin

Publication year - 2021

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.202000517

Subject(s) - dehydrogenation , chemistry , catalysis , pyridine , yield (engineering) , atom economy , organic chemistry , functional group , hydrogen , combinatorial chemistry , metallurgy , materials science , polymer

A silver catalyzed pyridine‐directed acceptorless dehydrogenation of secondary benzyl alcohols was developed. This general procedure delivers ketones with high atom‐economy and hydrogen was the sole byproduct. This dehydrogenation reaction has a good functional group tolerance and high efficiency (up to 90% yield and 10,000/1 substrates‐to‐catalyst ratio).

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