A pyrazine‐bridged trimer of oxo‐centered triruthenium–carbonyl clusters and the supramolecular assembly built from multiple noncovalent contacts | Zendy

Daicho Keita | Zendy; Ozawa Yoshiki | Zendy; Sugimoto Kunihisa | Zendy; Abe Masaaki | Zendy

Premium

A pyrazine‐bridged trimer of oxo‐centered triruthenium–carbonyl clusters and the supramolecular assembly built from multiple noncovalent contacts

Author(s) -

Daicho Keita,

Ozawa Yoshiki,

Sugimoto Kunihisa,

Abe Masaaki

Publication year - 2020

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.202000491

Subject(s) - pyrazine , chemistry , trimer , supramolecular chemistry , intermolecular force , crystallography , hydrogen bond , non covalent interactions , cluster (spacecraft) , crystal structure , supramolecular assembly , crystal (programming language) , single crystal , molecule , stereochemistry , dimer , organic chemistry , computer science , programming language

The crystal structure of a new pyrazine‐bridged trimer of oxo‐centered triruthenium–carbonyl clusters formulated as [Ru 3 O(EtCOO) 6 (CO)(pyrazine)] 2 [Ru 3 O(EtCOO) 6 (CO)(μ‐pyrazine) 2 ] ( 1 ) has been unequivocally determined by single‐crystal X‐ray diffraction (SC‐XRD) analysis at 100 K. A supramolecular cyclic assembly of two trimers was formed via intermolecular CO⋯CO contacts, which is further assembled into a three‐dimensional orthogonal layer‐by‐layer stack via hydrogen bonds.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research