Adsorption and reactions of  C 6   compounds with CC, C OH,  and/or CO groups on  TiO 2 | Zendy

Lin PoYuan | Zendy; Chien TzuEn | Zendy; Lai PoChih | Zendy; Shih YingChung | Zendy; Li KunLin | Zendy; Chung YuYin | Zendy; Liu YingXuan | Zendy; Lin JongLiang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Adsorption and reactions of C 6 compounds with CC, C OH, and/or CO groups on TiO 2

Author(s) -

Lin PoYuan,

Chien TzuEn,

Lai PoChih,

Shih YingChung,

Li KunLin,

Chung YuYin,

Liu YingXuan,

Lin JongLiang

Publication year - 2021

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.202000461

Subject(s) - chemistry , acetone , pinacol , thermal decomposition , decomposition , adsorption , mesityl oxide , medicinal chemistry , photochemistry , organic chemistry , catalysis

Acetone is generated upon mesityl oxide (MO) adsorption on TiO 2 at 35°C. Water plays an important role in promoting MO decomposition to form acetone. It is suggested that diacetone alcohol plays a role in the transformation of MO to acetone. The thermal reaction of pinacol on TiO 2 mainly produces pinacolone at a temperature higher than 100°C. However, acetone is mainly formed in the photocatalytic decomposition of pinacol on TiO 2 in O 2 . Pinacolone is thermally transformed into 2,3‐dimethyl‐1,3‐butadiene in the absence of O 2 and into pivalate in the presence of O 2 . Both the reactions of pinacolone occur above 200°C.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research