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Influence of Sr 2+ ion substitution on structural, morphological, optical, thermal, and magnetic behavior of MgFe 2 O 4 cubic spinel
Author(s) -
Baskar S,
Yuvaraj S,
Partha Sarathi Subudhi,
Sundararajan M,
Chandra Sekhar Dash
Publication year - 2021
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.202000319
Subject(s) - chemistry , spinel , endothermic process , analytical chemistry (journal) , crystallite , ferrite (magnet) , strontium , crystallography , materials science , metallurgy , organic chemistry , adsorption , chromatography , composite material
Utilizing L‐arginine as a fuel, Mg 1‐ x Sr x Fe 2 O 4 (0 ≤ x ≤ 0.5) spinel nanoparticles were prepared by the microwave combustion process. Impact of Sr 2+ ion substitution on structural, morphology, optical, thermal, and magnetic characteristics is investigated by following techniques such as X‐ray diffraction (XRD), HR‐SEM, energy dispersive X‐ray analysis (EDX), diffused reflectance spectroscopy‐Ultra Violet (DRS‐UV), TG‐DTA, and VSM. XRD ensures the formation of the cubic spinel structure, and the average crystallite size was determined utilizing the Debye Scherer equation, which was found to be lying between 33.10 and 24.11 nm. HR‐SEM images exhibited agglomerated morphology, and the samples were observed to be highly crystalline in nature. EDX spectra confirmed the formation of pure and strontium doped magnesium ferrite, ensuring the existence of all the elements. The bandgap was observed to lie in between 2.02 and 1.57 eV, respectively. TG‐DTA spectra provide information regarding the total weight loss, endothermic, and exothermic transitions. From M‐H loops, it is observed that pure and strontium doped magnesium ferrite exhibits ferromagnetic behavior.