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Multicomponent reaction of amine, carbon disulfide, and fluoronitrobenzene via nucleophilic attack on the fluorinated carbon for the synthesis of nitrophenyl methylcarbamodithioates
Author(s) -
Bahadorikhalili Saeed,
Mohammadi Sayyad,
Asadi Mehdi,
Barazandeh Maliheh,
Mahdavi Mohammad
Publication year - 2020
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201900111
Subject(s) - chemistry , carbon disulfide , nucleophile , amine gas treating , disulfide bond , carbon fibers , salt (chemistry) , combinatorial chemistry , reaction mechanism , organic chemistry , catalysis , biochemistry , materials science , composite number , composite material
In this paper, multicomponent reaction of amine, carbon disulfide and fluoronitrobenzene is reported for the synthesis of nitrophenyl methylcarbamodithioate derivatives. The method is based on the nucleophilic attack of the activated methylcarbamodithioate salt to fluoronitrobenzene. Several starting materials are tested and successfully produced the corresponding nitrophenyl methylcarbamodithioate. A possible mechanism for the reaction is suggested.