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The structures of MOFs prepared from 1,3,5‐tris [4‐pyridylethynyl]‐benzene and a copper(I) perchlorate complex
Author(s) -
Yang EnChe,
Wu ChenMing,
Pan PeiJia,
Lee GeneHsiang,
Sheu HwoShuenn,
Chang ChungKai
Publication year - 2019
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201900022
Subject(s) - chemistry , benzene , copper , perchlorate , tris , ligand (biochemistry) , pyridine , ion , inorganic chemistry , crystallography , polymer chemistry , medicinal chemistry , organic chemistry , biochemistry , receptor
Two copper(I)‐based frameworks of complexes {[Cu(L) 2 (ClO 4 )]⋅CH 3 CN}( 2 ) and {[Cu(L)(ClO 4 )]⋅ 2CH 3 CN} ( 3 ) (L = 1,3,5‐tris(4‐pyridylethynyl) benzene) were produced by reacting [Cu(MeCN) 4 (ClO 4 )] with different amounts of a ligand (L) using a hydrothermal method at temperatures of up to 130°C. The nitrogen atoms in the pyridine moieties of the ligand coordinate to the Cu(I) ion. The charge on the Cu(I) ion can be stabilized by extending the degree of conjugation in the system and by taking advantage of its highly symmetrical structure. The large degree of conjugation also supports numerous π–π interactions in the framework.