Bio‐inspired iron/sulfur/graphene nanocomposite and its use in the catalysis of the oxygen reduction reaction at room temperature in alkaline media on a glassy carbon electrode

This work demonstrates the performance of a bio‐inspired iron/sulfur/graphene nanocomposite as a non‐platinum electrocatalyst for the oxygen reduction reaction (ORR) in an alkaline medium. The catalyst shows the most positive ORR onset potential (1.1 V vs. RHE) according to its unique structure in the alkaline medium (KOH solution, pH = 13) at low temperature ( T = 298 K). The catalyst is evaluated by the rotating‐disk electrode (RDE) method under various rotating speeds (0–2,000 rpm) in the potential range −0.02–1.18 V vs. a rechargeable hydrogen electrode (RHE). The number of transferred electrons, as one of the most important parameters, is almost constant over a wide range of potentials (0.1–0.8 V), which indicates a more efficient four‐electron pathway from O 2 to H 2 O on the FePc‐S‐Gr surface. The mean size of catalyst centers are in the nanoscale (<10 nm). The estimated Tafel slope in the appropriate range is about −110 mV per decade at low current density, and E 1/2 of FePc‐S‐Gr displays a negative shift of only 7.1 mV after 10,000 cycles.