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Synthesis of hydrated furans: Analysis of the Prins reaction mechanism
Author(s) -
Sharipova Gulnaz M.,
Gerchikov Anatoly Ya.,
Safarova Irina V.,
Тukhvatshin Vadim S.,
Spivak Semen I.,
Ilyina Margarita G.
Publication year - 2019
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201800236
Subject(s) - chemistry , kinetic energy , furan , reaction mechanism , computational chemistry , elementary reaction , prins reaction , reaction rate constant , mechanism (biology) , thermodynamics , kinetics , organic chemistry , catalysis , philosophy , epistemology , physics , quantum mechanics
Mechanistic analysis of hydrogenated furan synthesis by the Prins reaction was carried out using mathematical modeling. The direct and inverse chemical kinetic problems are solved for the rate constants of all elementary steps. A probable mechanism is derived from the obtained quantitative kinetic parameters and the kinetic patterns of the reaction. These include kinetic curves from the concentration changes of all species in the reaction.