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Synthesis of a palladium complex bearing 2‐phenylbenzothiazole and its application to Suzuki–Miyaura coupling reaction
Author(s) -
Kosuru Someswara Rao,
Lai HsinYu,
Yang ChienYi,
Senadi Gopal Chandru,
Lai YiChun,
Chen HsuanYing
Publication year - 2019
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201800145
Subject(s) - chemistry , phenylboronic acid , benzothiazole , palladium , catalysis , suzuki reaction , coupling (piping) , bearing (navigation) , coupling reaction , medicinal chemistry , polymer chemistry , organic chemistry , stereochemistry , metallurgy , materials science , cartography , geography
The palladacycle complex [L s PdOAc] 2 bearing 2‐phenyl benzothiazole was synthesized and characterized by NMR and X‐ray crystallography. [L s PdOAc] 2 was used as a catalyst in the Suzuki–Miyaura cross coupling reaction of 4‐bromotoluene with phenylboronic acid, which resulted in a conversion of >90% with 5 mol% of the Pd complex within 10 min at 60°C.