Premium
Fabrication of Hexagonal Boron Nitride Nanosheets by Using a Simple Thermal Exfoliation Process
Author(s) -
Ko WenYin,
Chen ChengYu,
Chen WeiHung,
Lin KuanJiuh
Publication year - 2016
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201500335
Subject(s) - x ray photoelectron spectroscopy , boron nitride , raman spectroscopy , exfoliation joint , scanning electron microscope , transmission electron microscopy , chemistry , analytical chemistry (journal) , chemical engineering , nanotechnology , spectroscopy , materials science , graphene , composite material , organic chemistry , optics , physics , engineering , quantum mechanics
A simple and inexpensive method to exfoliate boron nitride powder to form boron nitride nanosheets (BNNSs) with few layers was achieved by using a physically thermal process. The obtained BNNSs were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), atomic force microscopy (AFM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), IR spectroscopy, and Raman spectroscopy. The size distribution of the sheets and average sheet size is in the range of 80–380 nm and 200±62 nm, respectively, and the pure phase h‐BN products were confirmed. XPS result showed the B/N atomic ratio to be 0.99. In addition, the BNNSs can well disperse in aqueous solution to form a cloudy suspension and importantly, can remain suspended for 1 month without precipitate, which would have good potential in a wide range of applications.