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Synthesis and Characterization of Novel Polyamines Containing Different Substitute Groups Via Chemical Oxidative Polymerization
Author(s) -
Senol Dilek,
Kaya ismet
Publication year - 2015
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201400525
Subject(s) - chemistry , cyclic voltammetry , polymerization , condensation polymer , polymer , electrochemistry , aqueous solution , amine gas treating , scanning electron microscope , polymer chemistry , nuclear chemistry , aromatic amine , organic chemistry , electrode , physics , quantum mechanics
In this study, polymers of substitute aromatic amine compounds were synthesized by chemical oxidative polycondensation in aqueous alkaline medium using NaOCl as oxidant. The structures of synthesized compounds were confirmed by FT‐IR, UV‐Vis and NMR analyses. The characterizations of synthesized compounds were made by fluorescence, TG‐DTA, DSC, scanning electron microscopy (SEM) and Brunauer‐Emmett‐Teller (BET) surface area measurements. In addition, electrochemical and electrical conductivity values of compounds were carried out with cyclic voltammetry (CV) and four points probe technique measurements, respectively. Synthesized polymers viewed structural change, optical, electrochemical and thermal differences.