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The First Triple‐Stranded Helical Metallosupramolecule with Metal Cluster Core
Author(s) -
Kao HsienChang,
Tang ShangWei,
Wang WenJwu
Publication year - 2014
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201400397
Subject(s) - chemistry , pyridazine , triple helix , core (optical fiber) , hydrazone , crystallography , ligand (biochemistry) , cluster (spacecraft) , metal , stereochemistry , organic chemistry , receptor , biochemistry , computer science , programming language , materials science , composite material
An unprecedented 3D framework, [Ag(Ag6(C2‐Me‐(Mepdz) 2 ) 3 (CH 3 CN)) 2 ](ClO 4 ) 13 , has been synthesized by using a ligand with both rigid pyridazine and flexible hydrazone segments, which represents to the best of our knowledge, the first example of metallosupramolecule built by the triple‐stranded helixes sharing the same penta‐silver core.