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Asymmetric Transfer Hydrogenation Catalyzed by Mesoporous MCM‐41‐Supported Chiral Ru‐Complex
Author(s) -
Sarkar Shaheen M.,
Yusoff Mashitah Mohd,
Rahman Md. Lutfor
Publication year - 2015
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201400319
Subject(s) - chemistry , transfer hydrogenation , mesoporous material , catalysis , mesoporous silica , mcm 41 , chiral ligand , combinatorial chemistry , enantioselective synthesis , asymmetric hydrogenation , ligand (biochemistry) , organic chemistry , ruthenium , biochemistry , receptor
Chiral N ‐sulfonyldiamine was successfully anchored on mesoporous MCM‐41 silica. The MCM‐41‐supported chiral N ‐sulfonyldiamine was used as an efficient heterogeneous chiral ligand in the asymmetric transfer hydrogenation of ketones. This heterogeneous system offered satisfactory enantioselectivities up to 94 % with excellent conversions.
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