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Supported Palladium Oxide Nanoparticles in SBA‐15 as a Heterogeneous Catalyst for the Aerobic Oxidation of Alcohols
Author(s) -
Atashin Hassan,
Malakooti Reihaneh
Publication year - 2014
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201300609
Subject(s) - chemistry , catalysis , palladium , alcohol oxidation , mesoporous silica , inductively coupled plasma , nanoparticle , decomposition , mesoporous material , adsorption , thermal decomposition , heterogeneous catalysis , desorption , inorganic chemistry , oxide , transmission electron microscopy , nuclear chemistry , chemical engineering , organic chemistry , plasma , physics , quantum mechanics , engineering
Abstract Palladium nanoparticles were first synthesized through the thermal decomposition method and subsequently immobilized on ordered mesoporous silica material, SBA‐15, to afford PdO/SBA‐15 catalyst. The synthesized catalyst was characterized by X‐ray diffraction, nitrogen adsorption‐desorption measurement, transmission electron microscopy, and inductively coupled plasma atomic emission spectrometry. The catalytic activity was tested for the aerobic oxidation of alcohols. Easy recovery, high yeilds and relatively short reaction times were observed for the mentioned catalyst.