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Water‐Soluble and Recyclable Cyclopalladated Ferrocenylimine for Suzuki Coupling Reaction
Author(s) -
Li Yang,
Fu Zhihua,
Rao Lu,
Wang Li,
Li Rui,
Li Tiesheng,
Wu Yangjie
Publication year - 2014
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201300353
Subject(s) - phenylboronic acid , chemistry , suzuki reaction , catalysis , aryl , coupling reaction , atmosphere (unit) , organic chemistry , coupling (piping) , boronic acid , polymer chemistry , nuclear chemistry , palladium , meteorology , mechanical engineering , alkyl , physics , engineering
A series of new water‐soluble cyclopalladated ferrocenylimines were designed and prepared. They were efficient catalyst for Suzuki coupling reactions of aryl bromides and phenylboronic acid in neat water under ambient atmosphere. Among of these catalysts, the catalyst ( C 2 D ) could be reused for 6 times for the Suzuki coupling reaction of 4‐bromotoluene with phenylboronic acid in EtOH/H 2 O under ambient atmosphere, in which no significant loss activity of C 2 D was observed.