Ruthenium Complexes with an Anthyridine‐based Ligand. Synthesis, Characterization and Catalytic Activity | Zendy

Lo YingHao | Zendy; Liu YiHung | Zendy; Peng ShieMing | Zendy; Liu ShiuhTzung | Zendy

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Ruthenium Complexes with an Anthyridine‐based Ligand. Synthesis, Characterization and Catalytic Activity

Author(s) -

Lo YingHao,

Liu YiHung,

Peng ShieMing,

Liu ShiuhTzung

Publication year - 2013

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.201300084

Subject(s) - chemistry , cyanation , ruthenium , catalysis , ligand (biochemistry) , medicinal chemistry , stereochemistry , organic chemistry , receptor , biochemistry

Complexation of 2,7‐bis(2‐pyridinyl)‐9‐phenylanthyridine ( 4 ) with [RuCl 2 (CO) 3 (THF)] and [(η 6 ‐ p ‐cymene)RuCl 2 ] 2 provided the mono‐nuclear complex [( 4 )Ru(CO) 3 Cl][RuCl 3 (CO) 3 ] ( 5 ) and the dinuclear complex [( 4 )Ru 2 ( p ‐cymene) 2 Cl 2 ] ( 6 ), respectively. Both complexes have been characterized by spectroscopic, elemental and crystallographic analyses. Complex 6 is an efficient catalyst for the oxidative cyanation of various tertiary arylamines.

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