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Ruthenium Complexes with an Anthyridine‐based Ligand. Synthesis, Characterization and Catalytic Activity
Author(s) -
Lo YingHao,
Liu YiHung,
Peng ShieMing,
Liu ShiuhTzung
Publication year - 2013
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201300084
Subject(s) - chemistry , cyanation , ruthenium , catalysis , ligand (biochemistry) , medicinal chemistry , stereochemistry , organic chemistry , receptor , biochemistry
Abstract Complexation of 2,7‐bis(2‐pyridinyl)‐9‐phenylanthyridine ( 4 ) with [RuCl 2 (CO) 3 (THF)] and [(η 6 ‐ p ‐cymene)RuCl 2 ] 2 provided the mono‐nuclear complex [( 4 )Ru(CO) 3 Cl][RuCl 3 (CO) 3 ] ( 5 ) and the dinuclear complex [( 4 )Ru 2 ( p ‐cymene) 2 Cl 2 ] ( 6 ), respectively. Both complexes have been characterized by spectroscopic, elemental and crystallographic analyses. Complex 6 is an efficient catalyst for the oxidative cyanation of various tertiary arylamines.