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Ti(O i ‐Pr) 4 Mediated Olefination between Julia Reagent and Aldehydes under Mild Conditions: Facile Synthesis of Vinyl Sulfones
Author(s) -
Yang Jinjin,
Yin Wei,
Liu Renhua,
Chu Changhu
Publication year - 2013
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201200466
Subject(s) - chemistry , reagent , organic chemistry , medicinal chemistry , combinatorial chemistry
A novel Ti(O i ‐Pr) 4 mediated olifination between Julia reagent and aldehydes has been developed. By this method, a series of substituted vinyl sulfones are prepared under mild conditions, all products are exclusively E isomers. All the structures of these compounds were confirmed by 1 H NMR, 13 C NMR HRMS and IR.