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Synthesis, Characterization and Properties of a Novel Environmentally Friendly Mono Azo Disperse Dye and Its Application on Polyethylene Terephthalate (PET)
Author(s) -
Dodangeh Mohammad,
Mohammadian Mehrdad,
Allen Norman. S.,
Pajootan Elmira
Publication year - 2013
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201200441
Subject(s) - dyeing , chemistry , disperse dye , polyethylene terephthalate , fourier transform infrared spectroscopy , chemical oxygen demand , alkaline hydrolysis , alkali metal , sublimation (psychology) , hydrolysis , reactive dye , environmentally friendly , proton nmr , polymer chemistry , nuclear chemistry , chemical engineering , organic chemistry , wastewater , composite material , waste management , materials science , engineering , psychology , ecology , psychotherapist , biology
The aim of this research is to achieve the synthesis of a novel mono azo disperse dye containing both a β‐naphthyl acetate group and carboxylic acid ester group and application on PET fabric. In this study the dyeing properties have also been investigated. The synthesized dye was characterized using UV‐Vis, FTIR, 1 H NMR and 13 C NMR spectroscopic techniques. To investigate alkali‐clearability, both alkali‐hydrolysis behavior and the effect of its fastness properties with regard to PET fabric were examined. This dye showed a reasonable level of hydrolysis under relatively mild alkaline conditions. The application of the dye to PET fabric showed good leveling and building up properties. Estimating fastness properties of the dyed fabric showed excellent wash, rubbing fastness, good light and sublimation fastness. The results furthermore displayed that the synthesized dye offers the option of alkali‐clearing process over that of a conventional reduction‐clearing process. Therefore, the value of Chemical Oxygen Demand (COD), Biological Oxygen Demand (BOD) and water pollution as well as the expenditure of production were decreased.