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Octanuclear Cu(I)‐dithiophosphates: An Efficient Catalyst System for N‐Arylation of Azoles, Amines, and Amides
Author(s) -
Wu ChengChieh,
Lee BoHan,
Liao PingKuei,
Fang ChingShiang,
Liu C. W.
Publication year - 2012
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201100592
Subject(s) - chemistry , catalysis , azole , combinatorial chemistry , medicinal chemistry , organic chemistry , antifungal , medicine , dermatology
The formation of a C‐N bond via the cross‐couplings of aryl iodides with azoles, aryl amine, and amides can be successfully achieved in decent yield by the utilization of both [Cu 8 (H){S 2 P(O i Pr) 2 } 6 ] + and [Cu 8 {S 2 P(OEt) 2 } 6 ] 2+ as the pre‐catalysts.