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Synthesis and Esterification of 3‐Ferrocenyl Acrylic Acid in Ionic Liquid
Author(s) -
Zhang WenSheng,
Xu WenJing,
Zhang Fei,
Wang YuZhe,
Li Jun,
Wang BaoAn,
Li Yan
Publication year - 2012
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201100536
Subject(s) - chemistry , hexafluorophosphate , ionic liquid , acrylic acid , yield (engineering) , acrylate , organic chemistry , polymer chemistry , ferrocene , phenols , catalysis , polymer , monomer , electrochemistry , materials science , metallurgy , electrode
3‐Ferrocenyl acrylic acid, synthesized from ferrocenecarboxaldehyde and propandioic acid in water‐insoluble ionic liquid (1‐butyl‐3‐methylimidazolium hexafluorophosphate, [BMIM]PF 6 ) at 85 °C in high yield, was transformed to a series of 3‐ferrocenyl acrylate of alcohols and phenols in water‐soluble ionic liquid (1,3‐dimethylimidazolium dimethylphosphate, [DMIM]Me 2 PO 4 ) at room temperature in the presence of dicyclohexylcarbodiimide (DCC) and 4‐dimethylaminopyridine (DMAP).