Synthesis and Esterification of 3‐Ferrocenyl Acrylic Acid in Ionic Liquid | Zendy

Zhang WenSheng | Zendy; Xu WenJing | Zendy; Zhang Fei | Zendy; Wang YuZhe | Zendy; Li Jun | Zendy; Wang BaoAn | Zendy; Li Yan | Zendy

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Synthesis and Esterification of 3‐Ferrocenyl Acrylic Acid in Ionic Liquid

Author(s) -

Zhang WenSheng,

Xu WenJing,

Zhang Fei,

Wang YuZhe,

Li Jun,

Wang BaoAn,

Li Yan

Publication year - 2012

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.201100536

Subject(s) - chemistry , hexafluorophosphate , ionic liquid , acrylic acid , yield (engineering) , acrylate , organic chemistry , polymer chemistry , ferrocene , phenols , catalysis , polymer , monomer , electrochemistry , materials science , metallurgy , electrode

3‐Ferrocenyl acrylic acid, synthesized from ferrocenecarboxaldehyde and propandioic acid in water‐insoluble ionic liquid (1‐butyl‐3‐methylimidazolium hexafluorophosphate, [BMIM]PF 6 ) at 85 °C in high yield, was transformed to a series of 3‐ferrocenyl acrylate of alcohols and phenols in water‐soluble ionic liquid (1,3‐dimethylimidazolium dimethylphosphate, [DMIM]Me 2 PO 4 ) at room temperature in the presence of dicyclohexylcarbodiimide (DCC) and 4‐dimethylaminopyridine (DMAP).

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