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Efficient and Convenient Oxidation of Organic Halides to Aldehydes and Ketones Catalyzed by H 5 IO 6 /V 2 O 5 in Ionic Liquid [bmpy][PF 6 ]
Author(s) -
Hu YuLin,
Liu Xiang,
Lu Ming,
Jiang Hui
Publication year - 2010
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.201000005
Subject(s) - chemistry , ionic liquid , halide , catalysis , solvent , extraction (chemistry) , organic solvent , organic chemistry , aldehyde , trace amounts , environmentally friendly , chemical engineering , medicine , ecology , alternative medicine , pathology , biology , engineering
A mild, efficient, and eco‐friendly procedure for the oxidation of organic halides to aldehydes and ketones in good to high yields catalyzed by H 5 IO 6 /V 2 O 5 in ionic liquid [bmpy][PF 6 ] with no trace of overoxidation to carboxylic acids has been developed. The product can be isolated by a simple extraction with organic solvent, and the catalytic system can be recycled or reused without any significant loss of catalytic activity.