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Effects of pH and Concentration on Cs Ions Sorption and Diffusion in Crushed Granite by Using Batch and Modified Capillary Method
Author(s) -
Wang TsingHai,
Li MingHsu,
Wei YuanYaw,
Teng ShiPing
Publication year - 2009
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200900111
Subject(s) - sorption , chemistry , diffusion , ion , adsorption , ion exchange , analytical chemistry (journal) , chromatography , mineralogy , thermodynamics , physics , organic chemistry
Abstract A comprehensive evaluation of Cs ions sorption to and diffusion in crushed granite was conducted in this study. The sorption capacity of crushed granite suggested by the Langmuir model was 5.48 × 10 −6 mol‐Cs/g‐granite. The distribution coefficient (Kd) was around 7.5 mL/g and pH independent. By using an in‐diffusion method with a modified capillary column, some diffusion relevant parameters of Cs ions in crushed granite were derived. The apparent diffusion coefficient ( Da ) seemed unaffected by Cs concentration (1.15 × 10 −10 to 2.82 × 10 −10 m 2 /s, at 10 −7 and 10 −3 M, respectively). The determined effective diffusion coefficients ( De ) were located in the window from 8.59 × 10 −10 (10 −7 M) to 1.69 × 10 −9 (10 −3 M) m 2 /s. Under various pH environments, pH independent Da (9.0 × 10 −9 m 2 /s) and De (1.0 × 10 −9 m 2 /s) values were observed. Under current systems, consistently higher De than Da implied the diffusion of Cs ions was governed by surface diffusion phenomenon. Whereas the pH insensitive feature indicated the Cs sorption to crushed granite was mainly through ion‐exchange reaction. Moreover, further SEM/EDS mapping clearly showed the adsorbed Cs ions were highly concentrated on the fracture surface of biotite.