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Hypervalent Iodine(III) Sulfonate Mediated Synthesis of α‐Thiocynanatoketones in a Task‐Specific Ionic Liquid [bmim]SCN
Author(s) -
Huang HsinYu,
Wang HueyMin,
Hou ReiSheu,
Cheng HuiTing,
Chen LingChing
Publication year - 2008
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200800179
Subject(s) - chemistry , ionic liquid , hypervalent molecule , iodine , sulfonate , aryl , medicinal chemistry , inorganic chemistry , alkyl , organic chemistry , sodium , catalysis
The task‐specific ionic liquid (TSIL) and 1‐n‐butyl‐3‐methylimidazolium thiocynanate, ([bmim]SCN) were used as the medium as well as the reactant for the synthesis of α‐thiocynanatoketones by the reaction with α‐sulfonyloxy aryl ketones. Significant rate enhancements and improved yields have been observed.