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The Transition State of Free Radical S H 2′ Reaction of Allyl Chloride with Organomercurial Study by Inverse Secondary α‐Deuterium Kinetic Isotope Effect
Author(s) -
Wu YuhWern,
Chen MingDar,
Yang JyhFerng
Publication year - 2008
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200800090
Subject(s) - chemistry , kinetic isotope effect , deuterium , free radical addition , photochemistry , free radical reaction , chloride , elimination reaction , medicinal chemistry , computational chemistry , radical , organic chemistry , physics , quantum mechanics
The concerted mechanism of free radical S H 2′ reaction of 2‐substituted allyl chloride was suggested again by inverse secondary α‐deuterium isotope effect. The transition state of free radical S H 2′ reaction of allyl chlorides seems to be symmetrical and is not as early as that of a free radical addition reaction.