The Transition State of Free Radical S H 2′ Reaction of Allyl Chloride with Organomercurial Study by Inverse Secondary α‐Deuterium Kinetic Isotope Effect | Zendy

Wu YuhWern | Zendy; Chen MingDar | Zendy; Yang JyhFerng | Zendy

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The Transition State of Free Radical S H 2′ Reaction of Allyl Chloride with Organomercurial Study by Inverse Secondary α‐Deuterium Kinetic Isotope Effect

Author(s) -

Wu YuhWern,

Chen MingDar,

Yang JyhFerng

Publication year - 2008

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200800090

Subject(s) - chemistry , kinetic isotope effect , deuterium , free radical addition , photochemistry , free radical reaction , chloride , elimination reaction , medicinal chemistry , computational chemistry , radical , organic chemistry , physics , quantum mechanics

The concerted mechanism of free radical S H 2′ reaction of 2‐substituted allyl chloride was suggested again by inverse secondary α‐deuterium isotope effect. The transition state of free radical S H 2′ reaction of allyl chlorides seems to be symmetrical and is not as early as that of a free radical addition reaction.

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