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N,N,N′,N′ ‐Tetraalkylaminoazoxybenzene Derivatives; Convenient Synthesis and Mechanistic Study
Author(s) -
Lai LongLi,
Chang YiGing,
Hsu HuiChu,
Hsu ShunJu,
Luo DaoWen
Publication year - 2007
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200700231
Subject(s) - chemistry , acetone , crystal structure , single crystal , mechanism (biology) , coupling reaction , reaction mechanism , medicinal chemistry , stereochemistry , crystallography , organic chemistry , catalysis , philosophy , epistemology
N,N,N′,N′ ‐tetraalkyaminoazoxybenzene derivatives were conveniently prepared by the coupling of N,N ‐dialkylnitrosoaniline in the presence of acetone and KOH. The reaction mechanism was proposed and investigated, and the structure of compound 3b was also confirmed by single crystal X‐ray diffractometry.