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Synthesis and Characterization of Dinuclear Ruthenium(II) Complexes Based on 4,4′‐Bipyridyl Type Bridging Ligands
Author(s) -
Guckian Adrian L.,
Browne Wesley R.,
Hjelm Johan,
Vos Johannes G.
Publication year - 2007
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200700165
Subject(s) - chemistry , ruthenium , electrochemistry , bridging (networking) , ethylene , stereochemistry , polymer chemistry , combinatorial chemistry , crystallography , organic chemistry , catalysis , electrode , computer network , computer science
The synthesis, spectroscopic, electrochemical and photophysical characterization of a series of dinuclear ruthenium(II) complexes of the type [(bpy) 2 Ru(NnN) 2 RuCl(bpy) 2 ](PF 6 ) 3 , where NnN = 4,4′‐bipyridyl (N0N), 1,2‐bis(4‐pyridyl)ethylene (NEN), 1,2‐bis(4‐pyridyl)ethane (N2N), and 4,4′‐trimethylenedipyridine (N3N) are reported. The photophysical and electrochemical properties are discussed with particular emphasis on the ability of the bridging ligands to support intercomponent interaction.