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A Versatile and Practical Synthesis of 1,1‐Diacetates from Aldehydes Catalyzed by Cyanuric Chloride
Author(s) -
Bandgar Babasaheb P.,
Joshi Neeta S.,
Kamble Vinod T.
Publication year - 2007
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200700069
Subject(s) - chemistry , cyanuric chloride , acetic anhydride , catalysis , organic chemistry , chloride , solvent , acetic acid
Structurally diverse aldehydes are successfully converted into 1,1‐diacetates with acetic anhydride using cyanuric chloride as a mild, convenient and inexpensive catalyst under solvent‐free conditions. The noteworthy features of the present system are shorter reaction times, and mild and solvent‐free conditions. Furthermore, it offers chemoselective protection of aldehydes.