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Single Crystal Structure Determination and Molecular Modeling of Ethyl 4‐{[4‐(Dodecanoyloxy)Phenyl]Diazenyl}Benzoate; Various Mesogenic Behaviors from Different Lengths of Alkyl Chains
Author(s) -
Lai LongLi,
Su FengYa,
Zhan KaiChao,
Cai YiLyang,
Liu YiHung,
Wang Yu
Publication year - 2007
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200700029
Subject(s) - mesogen , chemistry , alkyl , stacking , ethyl benzoate , liquid crystal , crystallography , stereochemistry , organic chemistry , liquid crystalline , physics , optics , phase (matter) , catalysis
The molecular stacking and conformation of ethyl 4‐{[4‐(dodecanoyloxy)phenyl]diazenyl}benzoate was established on the basis of crystallographic data and further compared with those of 4‐{[4‐(decanoyloxy)phenyl]diazenyl}benzoate and 4‐{[4‐(octanoyloxy)phenyl]diazenyl}benzoate. The variation of mesogenic behaviors resulting from the different lengths of alkyl chains was also studied.