Phenyliodine(III) Bis(Trifluoroacetate) Mediated Synthesis of 2‐Aryl‐1,2‐Benzisothiazol‐3(2 H )‐Ones in Ionic Liquid | Zendy

Wang HueyMin | Zendy; Liang IChian | Zendy; Hou ReiSheu | Zendy; Huang HsinYu | Zendy; Chen LingChing | Zendy

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Phenyliodine(III) Bis(Trifluoroacetate) Mediated Synthesis of 2‐Aryl‐1,2‐Benzisothiazol‐3(2 H )‐Ones in Ionic Liquid

Author(s) -

Wang HueyMin,

Liang IChian,

Hou ReiSheu,

Huang HsinYu,

Chen LingChing

Publication year - 2007

Publication title -

journal of the chinese chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.329

H-Index - 45

eISSN - 2192-6549

pISSN - 0009-4536

DOI - 10.1002/jccs.200700021

Subject(s) - chemistry , ionic liquid , hexafluorophosphate , trifluoroacetic acid , aryl , medicinal chemistry , pummerer rearrangement , organic chemistry , catalysis , acetic anhydride , alkyl

Treatment of N ‐aryl‐2‐(benzylthio)benzamides with phenyliodine(III) bis(trifluoroacetate) containing trifluoroacetic acid resulted in an interrupted Pummerer‐type reaction in ionic liquid 1‐ n ‐butyl‐3‐methylimidazolium hexafluorophosphate, [bmim][PF 6 ] to give 2‐aryl‐1,2‐benzisothiazol‐3(2 H )‐ones rather than the normal Pummerer‐type products.

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