Premium
Molybdatophosphoric Acid/NaNO 2 as an Efficient Procedure for the Chemoselective N‐Nitrosation of Secondary Amines
Author(s) -
Zolfigol Mohammad Ali,
Niknam Khodabakhsh,
Nazari Fariba
Publication year - 2006
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200600088
Subject(s) - chemistry , nitrosation , sodium nitrite , nano , gas phase , nitrite , phase (matter) , organic chemistry , combinatorial chemistry , chemical engineering , engineering , nitrate
A combination of molybdatophosphoric acid and sodium nitrite in the presence of wet SiO 2 was used as an effective nitrosating agent for the nitrosation of secondary amines under mild and heterogeneous conditions in good to excellent yields. Also, the results of a computational study are investigated in the gas phase for geometry and properties of proposed structures.