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Ferric Nitrate/Molibdatophosphoric Acid as a New and Efficient System in the Oxidative Deprotection of Trimethylsilyl Ethers to Corresponding Carbonyl Compounds under Solvent‐Free Conditions
Author(s) -
Zolfigol Mohammad Ali,
MohammadpoorBaltork Iraj,
Shiri Morteza
Publication year - 2006
Publication title -
journal of the chinese chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.329
H-Index - 45
eISSN - 2192-6549
pISSN - 0009-4536
DOI - 10.1002/jccs.200600071
Subject(s) - chemistry , trimethylsilyl , ferric , oxidative phosphorylation , solvent , catalysis , organic chemistry , nitrate , biochemistry
Oxidative deprotection of a variety of trimethylsilyl ethers were performed by Fe(NO 3 ) 3 .9H 2 O in the presence of H 3 PMo 12 O 40 .xH 2 O as catalyst at room temperature in good to high yields under solvent‐free conditions.
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